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Synthesis and Characterization of Ag2Se-Based Hybrid and Ternary Semiconductor Nanocrystals with potential termoelectric applications.

Abstract number:

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Meeting: The 16th European Microscopy Congress 2016

Session: Materials Science

Topic: Nanoparticles: from synthesis to applications

Presentation Form: Oral Presentation

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Pau Torruella Besa (1, 2), Mariona Dalmases (3, 2), Víctor Fernàndez-Altable (3, 2), Andreu Cabot (4), Maria Ibáñez (5), Jordi Llorca (6), Lluís López-Conesa (1, 2), Gemma Martín (1, 2), Sónia Estradé (1, 2), Francesca Peiró (1, 2)

1. LENS-MIND, Departament d'Electrònica, Universitat de Barcelona, Barcelona, Espagne 2. Institut de Nanociència i Nanotecnologia (IN2UB), Universitat de Barcelona, Barcelona, Espagne 3. Departament de Química Inorgànica, Universitat de Barcelona, Barcelona, Espagne 4. Functional Nanomaterials Group, Catalonia Institute for Energy Research – IREC, Sant Adrià del Besós, Espagne 5. Functional Nanomaterials Group, Catalonia Institute for Energy Research – IREC, Barcelona, Espagne 6. Institute of Energy Technologies and Centre for Research in NanoEngineering, Universitat Politècnica de Catalunya, Barcelona, Espagne

Keywords: Fischesserite, nanoparticles, Silver Selenide, Thermoelectricity

Ag2Se is a heavy-metal free, low band gap semiconductor that is currently attracting much attention in several fields. Remarkably, its high Seebeck coefficient and its low thermal conductivity have made of Ag2Se a definitely promising thermoelectric material. Considering that material nanostructuration often entails a significant increase of the ZT figure of merit with respect to the bulk, the synthesis and study of Ag2Se nanocrystals and of its nanostructured derivatives seems exciting and definitely deserves an effort.

With regard to the synthesis of metal-Ag2Se hybrid nanocrystals, very few examples are currently available in the literature and none of them has addressed their potential applications.

The aim of this work is studying the ternary Au-Ag-Se system at the nanoscale in order to figure out appropriate synthetic protocols for the controlled growth of hybrid and compositionally-controlled Ag2Se-based nanocrystals and perform an in-depth structural characterization of the materials obtained while also studying the thermoelectric potential of this new ternary nanosystem.

Figures:

Figure 1. HRTEM Image of the Ag3AuSe2 ternary semiconductor nanocrystals. Experimental image is compared to image simulations.

To cite this abstract:

Pau Torruella Besa, Mariona Dalmases, Víctor Fernàndez-Altable, Andreu Cabot, Maria Ibáñez, Jordi Llorca, Lluís López-Conesa, Gemma Martín, Sónia Estradé, Francesca Peiró; Synthesis and Characterization of Ag2Se-Based Hybrid and Ternary Semiconductor Nanocrystals with potential termoelectric applications.. The 16th European Microscopy Congress, Lyon, France. https://emc-proceedings.com/abstract/synthesis-and-characterization-of-ag2se-based-hybrid-and-ternary-semiconductor-nanocrystals-with-potential-termoelectric-applications/. Accessed: December 4, 2023
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